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Hwa Young Lee, Dr. Jungki Ryu, Jae Hong Kim, Sahng Ha Lee and Prof. Chan Beum Park Biocatalyzed Artificial Photosynthesis by Hydrogen-Terminated Silicon Nanowires ChemSusChem 5

Version of Record online: 3 SEP 2012 | DOI: 10.1002/cssc.201200251

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Down to the wires: A highly efficient artificial photosynthetic system employing hydrogen-terminated silicon nanowires is reported. The nanowires enable a cascading electron transfer from electron donor to NAD+ via a rhodium-based electron mediator. Approximately 80 % of NADH is photoregenerated from NAD+ by the nanowires during 2 h of light irradiation, and successfully coupled with the photoenzymatic synthesis of L-glutamate.

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