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Mehdi Salehi, Dr. Frank Clemens, Prof. Dr. Eugenio H. Otal, Dr. Davide Ferri, Prof. Dr. Thomas Graule and Prof. Dr. Bernard Grobéty Debinding Mechanisms in Thermoplastic processing of a Ba0.5Sr0.5Co0.8Fe0.2O3−δ- Stearic Acid–Polystyrene Mixture ChemSusChem 6

Version of Record online: 23 DEC 2012 | DOI: 10.1002/cssc.201200540

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Unusually active ceramics: This study analyses the role of a reactive ceramic powder during the thermal treatment of the thermoplastic feedstock. BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3−δ) in contrast to other ceramics, clearly participates in the decomposition reaction of polystyrene (PS). Owing to the release of oxygen by BSCF, the decomposition mechanism of PS in contact with the powder is changed from a pyrolytic to a thermoxidative mechanism.

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