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Dr. Peiyi Li, Khalaf Alenezi, Dr. Saad K. Ibrahim, Dr. Joseph A. Wright, Dr. David L. Hughes and Prof. Christopher J. Pickett Towards Alternatives to Anodic Water Oxidation: Basket-Handle Thiolate FeIII Porphyrins for Electrocatalytic Hydrocarbon Oxidation ChemSusChem 5

Article first published online: 3 SEP 2012 | DOI: 10.1002/cssc.201200572

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A preference for alcohol over oxygen: We show that iron porphyrins can mediate the anodic oxidation of hydrocarbons, thus providing a potential complementary reaction to cathodic generation of fuels or feedstocks as an alternative to oxygen evolution.

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