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Youngbo Choi, Dae Sung Park, Dr. Hyeong Jin Yun, Jayeon Baek, Danim Yun and Prof. Jongheop Yi Mesoporous Siliconiobium Phosphate as a Pure Brønsted Acid Catalyst with Excellent Performance for the Dehydration of Glycerol to Acrolein ChemSusChem 5

Version of Record online: 6 NOV 2012 | DOI: 10.1002/cssc.201200587

Thumbnail image of graphical abstract

Pore-ing over the details: A new mesoporous solid Brønsted acid is synthesized by combining niobium phosphate with silicate to give a homogeneous composite (see picture). The resulting composite has nearly pure Brønsted acidity, large mesopores, and moderate acid strength; this leads to the efficient and stable conversion of glycerol into acrolein.

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