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Dr. Mark D. Symes, Dr. Daniel A. Lutterman, Dr. Thomas S. Teets, Bryce L. Anderson, Prof. John J. Breen and Prof. Daniel G. Nocera Photo-active Cobalt Cubane Model of an Oxygen-Evolving Catalyst ChemSusChem 6

Article first published online: 3 JAN 2013 | DOI: 10.1002/cssc.201200682

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Down to the core: A soluble molecular model of a cobalt-based oxygen-evolving catalyst has been appended to ReI photosensitizers, giving rise to an unusual coordination complex consisting of an inorganic metal-oxo core tethered to two photo-sensitising oxidants. Substantial emission quenching of the ReI photocentres is evident upon irradiation at 355 nm.

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