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Dr. Saravanan Gowrisankar, Dr. Christopher Federsel, Dr. Helfried Neumann, Carolin Ziebart, Dr. Ralf Jackstell, Dr. Anke Spannenberg and Prof. Dr. Matthias Beller Synthesis of Stable Phosphomide Ligands and their Use in Ru-Catalyzed Hydrogenations of Bicarbonate and Related Substrates ChemSusChem 6

Article first published online: 28 DEC 2012 | DOI: 10.1002/cssc.201200732

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Ruthenium and phosphor work wonders: Air-stable ruthenium phosphomide complexes are active catalysts in the hydrogenation of sodium bicarbonate, carbon dioxide, and carbonyl compounds. Hydrogenation proceeds with high catalyst turnover numbers in the absence of amines or other additives. The application range of these new ruthenium catalysts also includes the hydrogenation of cinnamaldehyde and benzaldehyde.

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