E-mail a Wiley Online Library Link

Dr. Ivana Fleischer, Dr. Reiko Jennerjahn, Dr. Daniela Cozzula, Dr. Ralf Jackstell, Prof. Dr. Robert Franke  and Prof. Dr. Matthias Beller A Unique Palladium Catalyst for Efficient and Selective Alkoxycarbonylation of Olefins with Formates ChemSusChem 6

Article first published online: 15 JAN 2013 | DOI: 10.1002/cssc.201200759

Thumbnail image of graphical abstract

Forget about CO! Carbonylations are among the most important homogeneously catalyzed reactions in the chemical industry, but typically require carbon monoxide. Instead, straightforward and efficient alkoxycarbonylations of olefins can proceed with alkyl formates in the presence of a specific palladium catalyst. Aromatic, terminal aliphatic, and internal olefins are carbonylated to give industrially important linear esters at low catalyst loadings.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field