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Xiang Liu, Ran-Sheng Ding, Lin He, Dr. Yong-Mei Liu, Prof. Dr. Yong Cao, Prof. Dr. He-Yong He and Prof. Kang-Nian Fan C[BOND]C Cross-Coupling of Primary and Secondary Benzylic Alcohols Using Supported Gold-Based Bimetallic Catalysts ChemSusChem 6

Article first published online: 26 MAR 2013 | DOI: 10.1002/cssc.201200804

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Clean alcohol–alcohol cross-coupling: A clean and efficient one-pot direct C[BOND]C cross-coupling of equimolar amounts of primary and secondary alcohols by a facile hydrogen autotransfer pathway is achieved over a robust and easily recovered hydrotalcite-supported Au–Pd bimetallic catalyst system. A variety of primary and secondary alcohols have been selectively converted into the corresponding β-alkylated ketones in good yields.

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