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Dr. J. Johan Verendel, Michael Nordlund and Prof. Pher G. Andersson Selective Metal-Catalyzed Transfer of H2 and CO from Polyols to Alkenes ChemSusChem 6

Article first published online: 9 JAN 2013 | DOI: 10.1002/cssc.201200843

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Transmission of alcohols achieved: A method for the direct transfer of the CHOH function from simple polyols to alkenes has been developed. In a dual-reactor system, successive iridium-catalyzed dehydrogenations and decarbonylations of polyols such as glycerol and sorbitol generates a low pressure of syngas, which is directly used in ex situ alkene hydroformylation.

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