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Dr. Jianhui Wang, Prof. Ping Chen, Prof. Hongge Pan, Prof. Zhitao Xiong, Dr. Mingxia Gao, Dr. Guotao Wu, Dr. Chu Liang, Cao Li, Bo Li and Jieru Wang Solid–Solid Heterogeneous Catalysis: The Role of Potassium in Promoting the Dehydrogenation of the Mg(NH2)2/2 LiH Composite ChemSusChem 6

Version of Record online: 31 JUL 2013 | DOI: 10.1002/cssc.201200885

Thumbnail image of graphical abstract

Potassium is in the loop: The introduction of potassium to the Mg(NH2)2/2 LiH composite evolves intermediates of K2Mg(NH2)4, Li3K(NH2)4, and KH, which circularly transform between each other to create a more energy-favorable pathway for dehydrogenation, and thus contributes to the overall kinetic enhancement.

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