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Dr. Maksym Opanasenko, Dr. Amarajothi Dhakshinamoorthy, Dr. Young Kyu Hwang, Dr. Jong-San Chang, Prof. Hermenegildo Garcia and Prof. Jiří Čejka Superior Performance of Metal–Organic Frameworks over Zeolites as Solid Acid Catalysts in the Prins Reaction: Green Synthesis of Nopol ChemSusChem 6

Article first published online: 16 APR 2013 | DOI: 10.1002/cssc.201300032

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Green and efficient: Its high activity in the Prins condensation of β-pinene and paraformaldehyde, the preservation of its structure and active sites, and the possibility to use MIL-100 (Fe) in at least three catalytic cycles without loss of its activity are established. Our report exemplifies the advantages of MOFs over zeolites as solid catalysts in liquid-phase reactions for the production of fine chemicals.

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