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Dr. Loïc Leclercq, Roberto Company, Andrea Mühlbauer, Adrien Mouret, Prof. Dr. Jean-Marie Aubry and Prof. Dr. Véronique Nardello-Rataj Versatile Eco-friendly Pickering Emulsions Based on Substrate/Native Cyclodextrin Complexes: A Winning Approach for Solvent-Free Oxidations ChemSusChem 6

Version of Record online: 21 JUN 2013 | DOI: 10.1002/cssc.201300081

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Disperse and conquer! Solvent-less Pickering emulsions have been developed and applied to catalytic oxidation. The systems are stabilized by inclusion complexes between cyclodextrins and substrates forming a 3D network among the dispersed phase. In the presence of hydrogen peroxide as a green oxidant and [Na]3[PW12O40] as a catalyst, they provide particularly efficient eco-friendly reaction media for the oxidation of olefins, organosulfurs, and alcohols.

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