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Dr. Masayoshi Honda, Dr. Masazumi Tamura, Dr. Yoshinao Nakagawa, Satoru Sonehara, Dr. Kimihito Suzuki, Dr. Ken-ichiro Fujimoto and Prof. Dr. Keiichi Tomishige Ceria-Catalyzed Conversion of Carbon Dioxide into Dimethyl Carbonate with 2-Cyanopyridine ChemSusChem 6

Version of Record online: 25 JUN 2013 | DOI: 10.1002/cssc.201300229

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DMC run: Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2-cyanopyridine as a dehydration agent, catalyzed by CeO2. Regeneration of the coproduct 2-picolinamide can be achieved over a Na2O/SiO2 catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.

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