Zhijun Huang, Dr. Fengbo Li, Bingfeng Chen , Tao Lu , Yin Yuan and Prof. Guoqing Yuan A Sustainable Process for Catalytic Oxidative Bromination with Molecular Oxygen ChemSusChem 6
Workin′ in a bromine: A palladium–polyoxometalate amphiphilic hybrid material serves as catalyst for oxidative brominations. The emulsion-based process avoids the use of toxic and corrosive bromination agents such as Br2 or HBr, and uses molecular oxygen as oxidant. The only side product is water, which is also the reaction medium. The catalyst offers good recoverability and recyclability.
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