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Jia Jia Dong, Duenpen Unjaroen, Francesco Mecozzi, Dr. Emma C. Harvey, Dr. Pattama Saisaha, Dr. Dirk Pijper, Dr. Johannes W. de Boer, Dr. Paul Alsters, Prof. Dr. Ben L. Feringa and Prof. Dr. Wesley R. Browne Manganese-Catalyzed Selective Oxidation of Aliphatic C[BOND]H groups and Secondary Alcohols to Ketones with Hydrogen Peroxide ChemSusChem 6

Version of Record online: 5 SEP 2013 | DOI: 10.1002/cssc.201300378

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Manganeasy! MnII, picolinic acid, and butanedione make a smart mix for oxidation of secondary alcohols and alkanes and especially benzylic groups to ketones at room temperature with near stoichiometric amounts of hydrogen peroxide, low catalyst loadings, and high turn-over numbers.

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