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Youngkook Kwon, Dr. Ed de Jong, Saeed Raoufmoghaddam and Prof. Marc T. M. Koper Electrocatalytic Hydrogenation of 5-Hydroxymethylfurfural in the Absence and Presence of Glucose ChemSusChem 6

Version of Record online: 15 JUL 2013 | DOI: 10.1002/cssc.201300443

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A clean sweep: The hydrogenation of HMF in neutral media has been studied on a wide range of solid metal electrodes both in the absence and in the presence of glucose. From HMF hydrogenation, three groups of catalysts show affinities towards (1) DHMF, (2) DHMF and other products, depending on applied potentials, and (3) other products. HMF hydrogenation is shown to be preferred to glucose hydrogenation on all metals.

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