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Dr. Chun-Hong Kuo, Leo K. Lamontagne, Casey N. Brodsky, Lien-Yang Chou, Jia Zhuang, Brian T. Sneed, Margaret K. Sheehan and Prof. Chia-Kuang Tsung The Effect of Lattice Strain on the Catalytic Properties of Pd Nanocrystals ChemSusChem 6

Version of Record online: 17 SEP 2013 | DOI: 10.1002/cssc.201300447

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Shape up and ship out: Shape-controlled Pd nanocrystals have been synthesized with lattice strain generated from different sources. During electrocatalysis, decreased potentials for CO stripping and increased current densities for formic-acid oxidation are observed for the strained nanoparticles. In the gas-phase hydrogenation of ethylene, the activity of the strained nanoparticles was lower than that of single-crystalline Pd nanoparticles.

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