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Yong-Jun Yuan, Dr. Zhen-Tao Yu, Jian-Guang Cai, Dr. Chao Zheng, Prof. Dr. Wei Huang and Prof. Dr. Zhi-Gang Zou Water Reduction Systems Associated with Homoleptic Cyclometalated Iridium Complexes of Various 2-Phenylpyridines ChemSusChem 6

Version of Record online: 10 JUL 2013 | DOI: 10.1002/cssc.201300451

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Photo shy: A series of homoleptic tris-cyclometalated iridium(III) complexes are used for visible-light-induced hydrogen production with excellent activity and stability in the presence of [Rh(dtb-bpy)3]3+ as a water reduction catalyst and TEOA as an electron donor. This progress could pave the way towards the development of prolonged-lifetime and high-activity photocatalytic systems.

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