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Tian Lv, Yi Wang, Dr. Sang-Il Choi, Dr. Miaofang Chi, Dr. Jing Tao, Prof. Likun Pan, Prof. Cheng Zhi Huang, Dr. Yimei Zhu and Prof. Younan Xia Controlled Synthesis of Nanosized Palladium icosahedra and Their Catalytic Activity towards Formic-Acid Oxidation ChemSusChem 6

Version of Record online: 17 SEP 2013 | DOI: 10.1002/cssc.201300479

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Enhancement of catalytic activity by twin defects: Pd icosahedra with multiple twin defects and controlled sizes in the range of 5–35 nm are synthesized in high purity (>94 %) by manipulating reaction kinetics and show a higher catalytic activity towards formic-acid oxidation than single-crystal Pd octahedra and commercial Pd/C.

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