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Dr. Sanae El Ghachtouli, Dr. Regis Guillot, Dr. Francois Brisset and Prof. Ally Aukauloo Cobalt-Based Particles Formed upon Electrocatalytic Hydrogen Production by a Cobalt Pyridine Oxime Complex ChemSusChem 6

Version of Record online: 23 OCT 2013 | DOI: 10.1002/cssc.201300564

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Unexpected Co-operation: An open-coordination-sphere cobalt(III) pyridine oxime complex is designed as catalyst for the hydrogen evolution reaction (HER). However, electrochemical alteration in presence of acid leads to the formation of cobalt-based particles that act as efficient HER electrocatalyst at pH 7, pointing to the challenging task of identifying the real catalytic species in the development of new materials.

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