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Dr. Rosa Arrigo, Dr. Manfred E. Schuster, Dr. Salvatore Abate, Dr. Sabine Wrabetz, Kazuhiko Amakawa, Dr. Detre Teschner, Dr. Maria Freni, Prof. Gabriele Centi, Prof. Siglinda Perathoner, Dr. Michael Hävecker and Prof. Robert Schlögl Dynamics of Palladium on Nanocarbon in the Direct Synthesis of H2O2 ChemSusChem 7

Article first published online: 16 OCT 2013 | DOI: 10.1002/cssc.201300616

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Species elucidation: Palladium clusters with a modified electronic structure relative to bare palladium metal or palladium oxides allow selective active species for the direct synthesis of H2O2 (see picture). Nitrogen atoms in substitution positions in the carbon support accomplish the best strategy for the stabilization of the active palladium.

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