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Jyong-Yue Liu, Prof. Wei-Nien Su, Dr. John Rick, Dr. Sheng-Chiang Yang, Ju-Hsiang Cheng, Dr. Chun-Jern Pan, Dr. Jyh-Fu Lee and Prof. Bing-Joe Hwang Hierarchical Copper-Decorated Nickel Nanocatalysts Supported on La2O3 for Low-Temperature Steam Reforming of Ethanol ChemSusChem 7

Version of Record online: 4 DEC 2013 | DOI: 10.1002/cssc.201300737

Thumbnail image of graphical abstract

Unlikely allies: Cu/Ni nanocatalysts with a unique morphology are prepared by thermal reduction of a perovskite LaNixCu1−xO3 precursor (x=1, 0.9, and 0.7; see picture). Cu is released first during H2 pretreatment and forms a CuLa alloy. Next, mostly nanosized Ni is generated at a higher temperature before the CuLa alloy decomposes and Cu decorates the Ni nanoparticles.

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