Dr. Nathalie Clousier, Alexandra Filippi, Dr. Etienne Borré, Dr. Eric Guibal, Dr. Christophe Crévisy, Dr. Fréderic Caijo, Dr. Marc Mauduit, Dr. Isabelle Dez and Prof. Annie-Claude Gaumont Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis ChemSusChem 7
Powerful, reusable, and recyclable catalytic materials based on supported ionic liquid phase (SILP) technology for ruthenium ring-closing metathesis (RCM) and cross metathesis (CM) reactions are reported. The materials use alginate, a cheap, renewable and easily conditioned biopolymer, as support. Their excellent recyclability (15 cycles) combined with their high reactivity in either monophasic or biphasic conditions (use of cyclohexane) makes them excellent choices for RCM and CM reactions.
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