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Dr. Pradip Sarawade, Dr. Hua Tan, Dr. Dalaver Anjum, Dr. Dongkyu Cha and Prof. Dr. Vivek Polshettiwar Size- and Shape-Controlled Synthesis of Hexagonal Bipyramidal Crystals and Hollow Self-Assembled Al-MOF Spheres ChemSusChem 7

Version of Record online: 25 NOV 2013 | DOI: 10.1002/cssc.201300836

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MOFs shape up: A protocol is reported with which the size of hexagonal bipyramidal crystals of an Al metal–organic framework (Al-MOF) can be controlled in the 100–2000 nm range by changing the reaction duration and temperature through a nucleation–growth mechanism. A self-assembly phenomenon is also reported in which hollow spheres are formed by the spontaneous organization of triangular-sheet building blocks.

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