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Stefan A. W. Hollak, Maxim A. Ariëns, Prof. Dr. Krijn P. de Jong and Dr. Daan S. van Es Hydrothermal Deoxygenation of Triglycerides over Pd/C aided by In Situ Hydrogen Production from Glycerol Reforming ChemSusChem 7

Article first published online: 5 MAR 2014 | DOI: 10.1002/cssc.201301145

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With a little H2elp from my friends: A one-pot hydrolysis–deoxygenation reaction for triglycerides and free fatty acids, which is of particular interest for the production of biofuels and value-added chemicals from nonedible or waste fats and oils, is reported. The reaction is performed over palladium on carbon (Pd/C) at 250 °C without additional H2. Instead, in situ H2 production occurs through glycerol reforming and subsequent water–gas-shift reaction with a positive effect on the deoxygenation activity.

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