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Guanfeng Liang, Limin He, Prof. Masahiko Arai and Prof. Fengyu Zhao The Pt-Enriched PtNi Alloy Surface and its Excellent Catalytic Performance in Hydrolytic Hydrogenation of Cellulose ChemSusChem 7

Version of Record online: 24 MAR 2014 | DOI: 10.1002/cssc.201301204

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Put a Pt on it: ZSM-5-supported PtNi alloy particles with Pt-enriched alloy surface are prepared and characterized. The Pt-enriched alloy surface enhances hydrogenation activity but suppresses hydrogenolysis activity, thus resulting in high yield of hexitols. The decoration with an alloy surface offers a new approach to prevent the rapid deactivation of Ni-based catalysts in hot-compressed water.

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