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Michael E. Wilhelm, Michael H. Anthofer, Dr. Mirza Cokoja, Iulius I. E. Markovits, Prof. Dr. Wolfgang A. Herrmann and Prof. Dr. Fritz E. Kühn Cycloaddition of Carbon Dioxide and Epoxides using Pentaerythritol and Halides as Dual Catalyst System ChemSusChem 7

Article first published online: 24 MAR 2014 | DOI: 10.1002/cssc.201301273

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Doubleteam: The combination of pentaerytrithol with tetrabutylammonium iodide leads to an efficient catalytic system for the cycloaddition of carbon dioxide (CO2) with various epoxides to cyclic carbonates. The nontoxic, metalfree, and cost-efficient dual catalysts, as well as the easy recyclability result in an exceptional sustainable organocatalytic approach for the fixation of carbon dioxide.

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