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Mizuho Yabushita, Dr. Hirokazu Kobayashi, Prof. Jun-ya Hasegawa, Dr. Kenji Hara and Prof. Atsushi Fukuoka Entropically Favored Adsorption of Cellulosic Molecules onto Carbon Materials through Hydrophobic Functionalities ChemSusChem 7

Article first published online: 18 MAR 2014 | DOI: 10.1002/cssc.201301296

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Dual friendship: Hydrophobic functionality provides the primary and strong driving forces for adsorbing cellulosic molecules onto carbons (see picture). The driving forces consist of entropically driven hydrophobic interactions and CH–π hydrogen bonds, and thus, carbons can adsorb cellulosic molecules even at the high temperatures required for the conversion of cellulose.

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