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Thomas R. Gohndrone, Dr. Tae Bum Lee, Dr. M. Aruni DeSilva, Dr. Mauricio Quiroz-Guzman, Prof. William F. Schneider and Prof. Joan F. Brennecke Competing Reactions of CO2 with Cations and Anions in Azolide Ionic Liquids ChemSusChem 7

Version of Record online: 6 MAY 2014 | DOI: 10.1002/cssc.201400009

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Two different paths: Phosphonium azolide ionic liquids of interest for CO2 capture applications react with CO2 both through the normal anion channel and, at elevated temperatures, through a previously unrecognized cation channel. The cation channel involves a phosphonium ylide intermediate that is formed due to cation/anion interactions. This channel is suppressed with less-acidic ammonium cations.

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