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Dr. Chuan-Jun Wang, Dr. Shuang Cao, Dr. Biao Qin, Chen Zhang, Dr. Ting-Ting Li and Prof. Wen-Fu Fu Photoreduction of Iron(III) to Iron(0) Nanoparticles for Simultaneous Hydrogen Evolution in Aqueous Solution ChemSusChem 7

Version of Record online: 2 JUL 2014 | DOI: 10.1002/cssc.201400065

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Shedding light on an iron catalyst: A bifunctional noble-metal-free system for the photoreduction of Fe3+ to Fe(0) nanoparticles in water and simultaneous highly efficient photocatalytic hydrogen evolution is established. The sizes of the Fe nanoparticles generated in situ are tuned by changing the sacrificial donor from triethylamine to triethanolamine and by the introduction of H2N-MCM-41 or graphene into the photocatalytic system.

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