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Chengcheng Tian, Xiang Zhu, Dr. Song-Hai Chai, Dr. Zili Wu, Andrew Binder, Dr. Suree Brown, Dr. Lin Li, Dr. Huimin Luo, Dr. Yanglong Guo and Dr. Sheng Dai Three-Phase Catalytic System of H2O, Ionic Liquid, and VOPO4–SiO2 Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural ChemSusChem 7

Article first published online: 11 APR 2014 | DOI: 10.1002/cssc.201400119

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Set phases to stun! A three-phase catalytic system, consisting of an aqueous phase, a hydrophobic ionic-liquid phase, and a solid-acid catalyst phase of nanostructured vanadium phosphate and mesostructured cellular foam is developed for efficient conversion of biomass-derived fructose to 5-hydroxymethylfurfural. This unique three-phase catalytic system opens up an alternative avenue for making solid-acid catalyst systems with controlled microenvironment.

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