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Maxim V. Galkin and Dr. Joseph S. M. Samec Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis ChemSusChem 7

Version of Record online: 6 JUN 2014 | DOI: 10.1002/cssc.201402017

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Working in tandem: A tandem organosolv pulping and Pd-catalysed transfer hydrogenolysis depolymerization and deoxygenation method is developed to generate 2,6-dimethoxy-4-(prop-1-enyl)phenol in 49 % yield starting from birch wood. Only endogenous hydrogen from wood is consumed, and the reaction is performed using green solvents.

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