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Angela J. Kumalaputri, Dr. Giovanni Bottari, Petra M. Erne, Prof. Dr. Hero J. Heeres and Dr. Katalin Barta Tunable and Selective Conversion of 5-HMF to 2,5-Furandimethanol and 2,5-Dimethylfuran over Copper-Doped Porous Metal Oxides ChemSusChem 7

Version of Record online: 12 JUN 2014 | DOI: 10.1002/cssc.201402095

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With a little help from Ru: Selective and tunable hydrogenation of 5-hydroxymethylfurfural (HMF) with earth-abundant, copper-based porous metal oxides (Cu-PMOs) is achieved. Addition of a small amount of ruthenium dopant enhances the combined selectivity to 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF) under optimized conditions.

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