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Manu U. M. Patel and Dr. Robert Dominko Application of In Operando UV/Vis Spectroscopy in Lithium–Sulfur Batteries ChemSusChem 7

Article first published online: 8 JUL 2014 | DOI: 10.1002/cssc.201402215

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As it happens: A newly developed method for the deconvolution of UV/Vis spectra back into concentrations enables the study of the polysulfide shuttle mechanism in the different environments of lithium–sulfur batteries. The method is used to systematically study two different electrolytes. It is possible to distinguish the differences in the mechanism of polysulfide shuttling between two electrolytes and to correlate differences in capacity fading.

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