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Yu-Chiao Liu, Chia-Hsin Lee, Gene-Hsiang Lee and Ming-Hsi Chiang Influence of a Redox-Active Phosphane Ligand on the Oxidations of a Diiron Core Related to the Active Site of Fe-Only Hydrogenase European Journal of Inorganic Chemistry 2011

Article first published online: 24 JAN 2011 | DOI: 10.1002/ejic.201000972

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Ligation of mppf to the {Fe2S2} unitalters the oxidation levels of the Fe2 coreand improves stability of the oxidizedspecies.

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