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Souvik Roy, Sandip Shinde, G. Alexander Hamilton, Hilairy E. Hartnett and Anne K. Jones Artificial [FeFe]-Hydrogenase: On Resin Modification of an Amino Acid to Anchor a Hexacarbonyldiiron Cluster in a Peptide Framework European Journal of Inorganic Chemistry 2011

Article first published online: 17 NOV 2010 | DOI: 10.1002/ejic.201000979

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A general method for modification of a primary amine in peptides to create a dithiol anchor for metalloclusters is presented. The dithiol side chain is then used to construct a peptide-ligated [FeFe]-hydrogenase model.

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