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Yasuhiro Ohki and Kazuyuki Tatsumi Thiolate-Bridged Iron–Nickel Models for the Active Site of [NiFe] Hydrogenase European Journal of Inorganic Chemistry 2011

Version of Record online: 30 DEC 2010 | DOI: 10.1002/ejic.201001087

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[NiFe] hydrogenase is the most common type among the currently known hydrogenases, and its active site consists of an “organometallic” Fe–Ni complex supported by cysteinyl thiolate ligands. This review presents an overview of the synthesis, properties, and reactions of thiolate-bridged iron–nickel complexes that model the active site of [NiFe] hydrogenase.

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