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Vitaly Nesterov, Lili Duan, Gregor Schnakenburg and Rainer Streubel New Access to and Reactions of P-Functional Acylphosphane Complexes European Journal of Inorganic Chemistry 2011

Version of Record online: 27 DEC 2010 | DOI: 10.1002/ejic.201001122

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P-Functional (acylphosphane)tungsten complexes 2 were prepared in goodyields by the reaction of phosphinidenoid complexes 1 with acyl chlorides. The reactions of acyl(chloro)phosphane complexes2 (X = Cl; R = Ph) with organolithium reagents selectively led to the formation of phospha-enolate 3, which showed ambident reactivity towards electrophiles such as PhC(O)Cl, MeI, and Me3SiCl.

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