E-mail a Wiley Online Library Link

Vitaly Nesterov, Lili Duan, Gregor Schnakenburg and Rainer Streubel New Access to and Reactions of P-Functional Acylphosphane Complexes European Journal of Inorganic Chemistry 2011

Version of Record online: 27 DEC 2010 | DOI: 10.1002/ejic.201001122

Thumbnail image of graphical abstract

P-Functional (acylphosphane)tungsten complexes 2 were prepared in goodyields by the reaction of phosphinidenoid complexes 1 with acyl chlorides. The reactions of acyl(chloro)phosphane complexes2 (X = Cl; R = Ph) with organolithium reagents selectively led to the formation of phospha-enolate 3, which showed ambident reactivity towards electrophiles such as PhC(O)Cl, MeI, and Me3SiCl.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field