E-mail

E-mail a Wiley Online Library Link

Marcetta Y. Darensbourg and Wolfgang Weigand Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases – A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity European Journal of Inorganic Chemistry 2011

Version of Record online: 3 FEB 2011 | DOI: 10.1002/ejic.201001148

Thumbnail image of graphical abstract

An overview of the oxygen sensitivity of [NiFe] and [FeFe] hydrogenase and studies of oxygen reactivity with synthetic analogues of the enzyme active site are presented. Discrete S-oxygenate complexes that maintain the Ni-S or Fe-S connectivity could signify reversible oxygen damage, and a protective, “antioxidant” role of the sulfur atoms in the active sites.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH