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Daniel Streich, Michael Karnahl, Yeni Astuti, Clyde W. Cady, Leif Hammarström, Reiner Lomoth and Sascha Ott Comparing the Reactivity of Benzenedithiolate- versus Alkyldithiolate-Bridged Fe2(CO)6 Complexes with Competing Ligands European Journal of Inorganic Chemistry 2011

Version of Record online: 26 JAN 2011 | DOI: 10.1002/ejic.201001152

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Exposure of [(μ-bdt)Fe2(CO)6], (bdt)1, to secondary amines or dmf results in major structural changes of the complex and formation of a magnetically uncoupled FeI species that carries the bdt and CO ligands. This reactivity contrasts that of [(μ-edt)Fe2(CO)6], (edt)1, and [(μ-pdt)Fe2(CO)6], (pdt)1, which are unreactive under identicalconditions (bdt, edt, pdt = benzene-, ethyl-, propyldithiolate, respectively).

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