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Raja Angamuthu, Maria E. Carroll, Maya Ramesh and Thomas B. Rauchfuss A New Route to Azadithiolato Complexes European Journal of Inorganic Chemistry 2011

Article first published online: 14 JAN 2011 | DOI: 10.1002/ejic.201001208

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Azadithiolate (S–CH2–NH–CH2–S) is one of the unusual cofactors of the [FeFe]-hydrogenase enzyme. Reaction of [(MeC5H4)2Ti(SH)2] with cyclic imines with the formula (CH2NR)3 gives 2-aza-1,3-dithiolato chelate complexes [(MeC5H4)2Ti{(SCH2)2NR}]. These compounds demonstrate that azadithiolate ligands can exist on mononuclear metal centers.

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