E-mail a Wiley Online Library Link

Sarah K. Russell, Amanda C. Bowman, Emil Lobkovsky, Karl Wieghardt and Paul J. Chirik Synthesis and Electronic Structure of Reduced Bis(imino)pyridine Manganese Compounds European Journal of Inorganic Chemistry 2012

Version of Record online: 5 OCT 2011 | DOI: 10.1002/ejic.201100569

Thumbnail image of graphical abstract

The chemistry of reduced aryl-substituted bis(imino)pyridine manganese complexes has been explored with the goal of elucidating the role of the redox-active chelate. The bis(THF) derivative [(iPrPDI)Mn(THF)2] is a high-spin MnII complex antiferromagnetically coupled to a bis(imino)pyridine diradical, while the related dicarbonyl complex is a low-spin MnI, d6 derivative with a ligand-based SOMO.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field