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Sarah K. Russell, Amanda C. Bowman, Emil Lobkovsky, Karl Wieghardt and Paul J. Chirik Synthesis and Electronic Structure of Reduced Bis(imino)pyridine Manganese Compounds European Journal of Inorganic Chemistry 2012

Version of Record online: 5 OCT 2011 | DOI: 10.1002/ejic.201100569

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The chemistry of reduced aryl-substituted bis(imino)pyridine manganese complexes has been explored with the goal of elucidating the role of the redox-active chelate. The bis(THF) derivative [(iPrPDI)Mn(THF)2] is a high-spin MnII complex antiferromagnetically coupled to a bis(imino)pyridine diradical, while the related dicarbonyl complex is a low-spin MnI, d6 derivative with a ligand-based SOMO.

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