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Daniela Intrieri, Alessandro Caselli, Fabio Ragaini, Piero Macchi, Nicola Casati and Emma Gallo Insights into the Mechanism of the Ruthenium–Porphyrin-Catalysed Allylic Amination of Olefins by Aryl Azides European Journal of Inorganic Chemistry 2012

Version of Record online: 15 NOV 2011 | DOI: 10.1002/ejic.201100763

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The [Ru(TPP)CO]-catalysed synthesis of allylic amines was performed by employing aryl azides (ArN3) as nitrogen sources. A mechanistic hypothesis for the nitrene transfer reaction to cyclohexene was proposed on the basis of synthetic, spectroscopic and kinetic studies.

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