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Tek Long Chan, Ching Tat To, Bei-Sih Liao, Shiuh-Tzung Liu and Kin Shing Chan Electronic Effects of Ligands on the Cobalt(II)–Porphyrin-Catalyzed Direct C–H Arylation of Benzene European Journal of Inorganic Chemistry 2012

Version of Record online: 10 NOV 2011 | DOI: 10.1002/ejic.201100780

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The electronic effects of porphyrin ligands on the cobalt(II)–porphyrin-catalyzed direct C–H arylation were studied. The reaction rates were found to be dependent on the electronic richness of the porphyrin ligands. Additional axial ligands did not aid the rate-determining abstraction of theiodine atom.

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