E-mail a Wiley Online Library Link

Megumi Watanabe, Yohei Kashiwame, Shigeki Kuwata and Takao Ikariya Synthesis, Structures, and Transfer Hydrogenation Catalysis of Bifunctional Iridium Complexes Bearing a C–N Chelate Oxime Ligand European Journal of Inorganic Chemistry 2012

Version of Record online: 10 OCT 2011 | DOI: 10.1002/ejic.201100800

Thumbnail image of graphical abstract

A series of organometallic oxime complexes featuring a β-protic OH group have been synthesized. The hydrido-bridgedoxime–oximato complex (pictured) dissociates into two mononuclear species, which are interconvertible through reactions with hydrogen donors and acceptors. Owing to the metal–ligand cooperation, catalytic transfer hydrogenation of ketones with 2-propanol has been achieved.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field