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Frederic W. Patureau, Maxime A. Siegler, Anthony L. Spek, Albertus J. Sandee, Sylvain Jugé, Sarwar Aziz, Albrecht Berkessel and Joost N. H. Reek Supramolecular Hydrogen-Bonding Tautomeric Sulfonamido–Phosphinamides: A Perfect P-Chirogenic Memory European Journal of Inorganic Chemistry 2012

Article first published online: 28 SEP 2011 | DOI: 10.1002/ejic.201100811

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Supramolecular hydrogen-bonding sulfonamido–phosphinamides exist as a mixture of tautomers (PIII/PV) in slow equilibrium on the NMR spectroscopic timescale(METAMORPhos). The tautomeric process retains the configuration at the P centre, even in protic solvents. Their resolution allowed up to 99 % ee.

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