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Sebastian D. Pike, Rebekah J. Pawley, Adrian B. Chaplin, Amber L. Thompson, Joel A. Hooper, Michael C. Willis and Andrew S. Weller Exploring (Ph2PCH2CH2)2E Ligand Space (E = O, S, PPh) in RhI Alkene Complexes as Potential Hydroacylation Catalysts European Journal of Inorganic Chemistry 2011

Version of Record online: 14 NOV 2011 | DOI: 10.1002/ejic.201100958

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A variety of RhI cations [Rh{(Ph2PCH2CH2)2E}(alkene)]+ (E = PPh, S, O; alkene = methyl acrylate and trimethylvinylsilane) have been prepared and their fluxional behaviour investigated by variable-temperature NMR spectroscopy.

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