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Mark R. Ringenberg and Thomas B. Rauchfuss Protonation-Enhanced Lewis Acidity of Iridium Complexes Containing Noninnocent Amidophenolates European Journal of Inorganic Chemistry 2012

Version of Record online: 24 NOV 2011 | DOI: 10.1002/ejic.201101011

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Not just redox: Noninnocent ligands exhibit rich acid–base behavior. Protonation of noninnocent anilidophenolates induces the binding of Lewis bases (CO, PR3, MeCN).Bulky Lewis bases stabilize O-protonation, whereas smaller bases give N-protonated products.

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