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Kagna Ouch, Mark S. Mashuta and Craig A. Grapperhaus Alkyne Addition to a Metal-Stabilized Thiyl Radical: Carbon–Sulfur Bond Formation between 1-Octyne and [Ru(SP)3]+ European Journal of Inorganic Chemistry 2012

Version of Record online: 1 DEC 2011 | DOI: 10.1002/ejic.201101016

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The addition of 1-octyne to an electrophilic metal-stabilized thiyl radical complex has been induced through chemical and electrochemical oxidation. The alkyne adds irreversibly across the cis-sulfur sites of the metal-thiolate precursor to yield an S-alkylated dithiolene product complex.

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