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Cameron A. Lippert, Korbinian Riener and Jake D. Soper Aerobic Alcohol Oxidations Catalyzed by Oxorhenium Complexes Containing Redox-Active Ligands European Journal of Inorganic Chemistry 2012

Version of Record online: 24 NOV 2011 | DOI: 10.1002/ejic.201101044

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The capacity of oxorhenium(V) anions with redox-active catecholate ligands to homolyze O2 and generate dioxorhenium(VII) products is utilized for oxidase-type alcohol oxidations. Formation of the active oxidant requires both the dioxo and monooxo species. The scope and limitations of this redox-active ligand-mediated catalysis are discussed.

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